Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative     

Volkan Numan Bulut  Mehmet Tufekci  Celal Duran  Mustafa Soylak  Halit Kantekin 《洁净——土壤、空气、水》2010,38(7):678-683

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.  相似文献   

复杂应力条件下掺砾黏土真三轴试验     

张坤勇  朱俊高  吴晓铭  李永红 《岩土力学》2010,31(9):2799-2804

采用新型真三轴仪器,对掺砾黏土进行了复杂应力条件下加载试验,近似模拟了土石坝填筑期心墙土体单元的加荷过程。试验结果表明,由于土体单元处于复杂应力状态,即使是单向加载这样的简单加荷应力路径,在不同应力方向上的应力和变形也都呈现显著的应力各向异性。土石坝应力变形分析中坝体单元处于三向应力条件下,由于加载引起的应力各向异性对心墙乃至整个坝体的应力变形规律都有较大影响,合理的本构模型应该能够反映并描述这种复杂应力状态下的应力各向异性。  相似文献   

近20年青海湖湖水面积变化遥感   总被引：11，自引：6，他引：5  

刘瑞霞  刘玉洁 《湖泊科学》2008,20(1):135-138

采用NOAA/AVHRR资料,对青海湖湖面进行水体判识,并利用线性混合模式对混合象元进行处理,定量估算了近20年青海湖湖水面积并分析了变化趋势,表明近20年青海湖湖水面积在不断减小,每年减少约4km2,并且青海湖干涸部分主要在其北部.进一步采用主成分分析和回归分析方法对青海湖地区降水、气温和蒸发量做了初步气候分析,表明青海湖地区降水减少、气温升高、蒸发量增加是青海湖湖水面积逐年减少的主要原因.  相似文献   

Simulation of the ocean surface mixed layer under the wave breaking   总被引：6，自引：4，他引：2  

SUN Qun  SONG Jinbao  GUAN Changlong 《海洋学报(英文版)》2005,24(3):9-15

A one-dimensional mixed-layer model, including a Mellor-Yamada level 2.5 turbulence closure scheme, was implemented to investigate the dynamical and thermal structures of the ocean surface mixed layer in the northern South China Sea. The turbulent kinetic energy released through wave breaking was incorporated into the model as a source of energy at the ocean surface, and the influence of the breaking waves on the mixed layer was studied. The numerical simulations show that the simulated SST is overestimated in summer without the breaking waves. However, the cooler SST is simulated when the effect of the breaking waves is considered, the corresponding discrepancy with the observed data decreases up to 20% and the MLD calculated averagely deepens 3.8 m. Owing to the wave-enhanced turbulence mixing in the summertime, the stratification at the bottom of the mixed layer was modified and the temperature gradient spread throughout the whole thermocline compared with the concentrated distribution without wave breaking.  相似文献   

高水速凝材料-软土微观结构的SEM研究   总被引：5，自引：2，他引：3  

颜志平 《岩土力学》2004,25(2):275-282

高水速凝材料是一种新型的固体混合材料,它与普通硅酸盐水泥相比有许多独特的特点：(1) 水用量大;(2) 速凝早强;(3) 可泵时间长;(4) 良好的塑性特性;(5) 极限荷载后强度具再发展性能。虽然,高水速凝材料在煤炭和冶金系统得到了较广泛的应用,取得了较好的技术经济效益,然而,在其它领域还未曾应用过。为了探索高水速凝材料在软土地基方面的应用前景,笔者采用扫描电镜研究了高水速凝材料-软土凝固体的微观结构。研究结果表明,纯土的土颗粒之间只有原生矿物的几何堆积,而没有牢固的连接。但由于高水速凝材料的加入,彻底改变了土体结构。在高水速凝材料-软土凝固体中,主体结构为钙矾石结晶体形成的“空间网状结构”;辅助结构为在碱性环境中土颗粒之间的离子交换、团粒化作用和碳酸化作用所形成的微晶体与凝胶体结构。因此,高水速凝材料在地基处理方面具有较好的应用前景。  相似文献   

三维地下水流中常规观测孔水位的形成机理及确定方法   总被引：5，自引：1，他引：4  

陈崇希 《地球科学》2003,28(5):483-491

对地下水三维流中常规观测孔中水位的传统计算方法提出质疑, 认为计算观测孔中水位的Hantush Бочевер方程是缺乏物理基础的纯数学方法.分析了形成观测孔中水位的机理, 提出三维地下水流中常规观测孔中只是孔口的流量为零, 而孔内却存在"抽水"和"注水"的井孔; 多层井(multilayerwell) 不一定要求"多层"的条件, 在均质单一含水层中的井孔可以具有多层井的基本特征; 混合井孔的水位并不"混合", 混合观测孔中存在符合机理的水头分布和流量分布规律等观点.普遍而言, 三维流中的观测孔不能用通常所说的线汇/线源刻画, 也不能用近几年提出的孔内为层流(线性流) 的假定来研究该问题, 然而可用笔者于1993年提出的"渗流-管流耦合模型"和"等效渗透系数"方便、有效地模拟.就说明性算例而言, Hantush Бочевер方程只能近似用于孔径大于0.2m且径距大于10~20m的条件.   相似文献   

考虑三向应力效应的最大Mises应力复合断裂判据     

栾茂田  杨新辉  杨庆  樊成  叶祥记 《岩土力学》2006,27(10):1647-1652

通过对脆性断裂过程中开裂扩展机理的分析,提出了径向平面最大Mises应力(RPMS)概念。在平面应变条件下考虑泊松比的影响,对不同应力复合比的I-II复合型载荷作用下裂尖处应力分布进行了分析,以此为基础,考虑裂尖处三向应力状态对断裂过程的影响,将径向平面上的最大Mises应力作为裂纹开裂扩展的控制因素。据此,针对复合型载荷模式,提出了裂尖复合脆性断裂判据及裂纹开裂方向表达式。将计算结果与现有试验或其他理论进行了对比分析,以此验证了该径向平面上最大Mises应力断裂判据的合理性。  相似文献   

典型喀斯特地区马尾松纯林及马尾松-阔叶树混交林营养元素生物循环研究——以贵州龙里为例   总被引：3，自引：0，他引：3  

李茜  杨胜天  盛浩然  盛岩  李巍  李顺江 《中国岩溶》2008,27(4):321-328

以龙里典型喀斯特地区马尾松纯林及马尾松- 阔叶树混交林为研究对象,研究了两个群落的生物量、营养元素贮量、分布及循环特征。结果表明: 马尾松纯林、马尾松- 阔叶树混交林的生物量分别为40. 62t /hm2、48. 32t /hm2 ,混交林的乔木层总生物量比马尾松纯林高18. 97% ,根系生物量较纯林高65. 12%。混交林乔木层各器官营养元素的含量整体大于马尾松纯林,两群落乔木层N、P、K、S的含量表现出一致的趋势,叶> 根> 枝> 干。混交林乔木层各元素的积累量分别比纯林高47. 97%～ 197. 67% ,凋落物层各元素贮量比纯林高85. 40%～ 318. 301%。混交林的年归还量、年存留量和年吸收量均大于马尾松纯林,且各元素循环系数大于马尾松纯林。马尾松林与阔叶树混交可以有效地提高群落生物量和营养元素循环的能力。   相似文献   

掺砾黏土拉伸断裂细观特性研究     

袁会娜  张骏  张其光 《岩土力学》2016,37(11):3096-3104

掺砾黏土在高心墙堆石坝工程中的应用越来越广泛,其拉伸断裂特性对心墙的安全至关重要。将掺砾黏土视作四相复合材料,基于图像处理和随机投放建立了考虑真实砾石形态的细观数值模型,结合物理试验的结果验证了其有效性,并分析了掺砾黏土拉伸断裂的宏细观特性。应力位移曲线的宏观非线性是细观非均质性的体现,砾石的掺入大幅减低了抗拉强度,但提高了峰后抗拉性能;土石界面是微裂缝发展的源头,拉伸断裂是一个微裂缝萌生、扩展以至汇集形成宏观裂缝的过程;拉伸断裂发生在一个区域,即断裂过程区,该区域的形成与砾石的随机分布有关。最后,采用数值试验分析了随机砾石投放和掺砾量对掺砾黏土宏细观力学行为的影响。  相似文献   

Precipitation water storage capacity in a temperate mixed oak–beech canopy     

Frédéric André  Mathieu Jonard  Quentin Ponette 《水文研究》2008,22(20):4130-4141

The storage capacity of a temperate mixed oak–beech stand was investigated as a function of stand density and species composition. Measurements were performed in selected zones delimited by three neighbouring trees. Three independent approaches were compared: (i) a spraying laboratory experiment to estimate the water storage on foliage before and after dripping; (ii) a mechanistic model describing rainfall partitioning within the forest canopy and providing estimates of foliage storage capacities; and (iii) linear regression analyses to evaluate the canopy (foliage + branches) storage capacity using the relationship between throughfall and rainfall. Good agreement was generally observed between the laboratory experiment and the mechanistic model estimates, while estimations from the regression method tended to exceed those from the other approaches. Storage capacity estimates ranged from 0·22 mm to 0·80 mm for pure oak zones, from 0·24 mm to 1·12 mm for mixed zones and from 0·53 mm to 1·17 mm for pure beech zones. The increase of storage capacity with increasing proportion of beech in the canopy resulted from higher beech LAI compared with oak. Similarly, for mixed and pure beech canopies, storage capacity was higher for high density zones than for low density zones as a result of the increase in LAI with increasing local basal area; in contrast, for pure oak, the storage capacity was not related to basal area because of the lower shade‐tolerance of this species compared with beech. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献